In the Miller–Urey experiment they produced several amino acids. I'm not sure if there were other similar experiments that got further.
http://www.jcvi.org/cms/press/press-releases/full-text/article/first-self-replicating-synthetic-bacterial-cell-constructed-by-j-craig-venter-institute-researcher/ is a reference to making a cell, but they really injected an engineered genome into an existing cell (which is pretty amazing!)
But I'm interested in work to make completely synthetic life with no preexisting biological components.
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